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981.
In this article,we study the generalized Riemann problem for a scalar nonconvex Chapman-Jouguet combustion model in a neighborhood of the origin (t > 0) on the (x,t) plane.We focus our attention to the... 相似文献
982.
Alexander Gluhovsky Christopher Tong 《Communications in Nonlinear Science & Numerical Simulation》2012,17(7):3112-3113
Extensive prior literature (not referenced in the paper) on links between mechanical gyrostats and nonlinear dynamical systems with strange attractors is called to the readers’ attention. 相似文献
983.
Dr. Quentin Bonnin Tereza Edlová Dr. E. Daiann Sosa Carrizo Prof. Dr. Paul Fleurat-Lessard Dr. Stéphane Brandès Dr. Hélène Cattey Dr. Philippe Richard Prof. Dr. Pierre Le Gendre Dr. Adrien T. Normand 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(72):18175-18187
Cationic amidotitanocene complexes [Cp2Ti(NPhAr)][B(C6F5)4] (Cp=η5-C5H5; Ar=phenyl ( 1 a ), p-tolyl ( 1 b ), p-anisyl ( 1 c )) were isolated. The bonding situation was studied by DFT (Density Functional Theory) using EDA-NOCV (Energy Decomposition Analysis with Natural Orbitals for Chemical Valence). The polar Ti−N bond in 1 a–c features an unusual inversion of σ and π bond strengths responsible for the balance between stability and reactivity in these coordinatively unsaturated species. In solution, 1 a–c undergo photolytic Ti−N cleavage to release Ti(III) species and aminyl radicals ⋅ NPhAr. Reaction of 1 b with H3BNHMe2 results in fast homolytic Ti−N cleavage to give [Cp2Ti(H3BNHMe2)][B(C6F5)4] ( 3 ). 1 a–c are highly active precatalysts in olefin hydrogenation and silanes/amines cross-dehydrogenative coupling, whilst 3 efficiently catalyzes amine-borane dehydrogenation. The mechanism of olefin hydrogenation was studied by DFT and the cooperative H2 activation key step was disclosed using the Activation Strain Model (ASM). 相似文献
984.
Mahasin F. Hadi Al-Kadhemy 《Physica B: Condensed Matter》2012,407(17):3335-3338
The influence of the thickness of CdTe/n-Ge heterojunction photodetectors on I–V curves was studied experimentally and theoretically. The thicknesses of the CdTe thin films were 110, 130, 150, and 200 nm. The power intensity of illumination was 150 mW/cm2. Increasing the thickness led to an increase in photocurrent. 相似文献
985.
Infrastructure systems such as power and water supplies make up the cornerstone of modern society which is essential for the functioning of a society and its economy. They become more and more interconnected and interdependent with the development of scientific technology and social economy. Risk and vulnerability analysis of interdependent infrastructures for security considerations has become an important subject, and some achievements have been made in this area. Since different infrastructure systems have different structural and functional properties, there is no universal all-encompassing ‘silver bullet solution’ to the problem of analyzing the vulnerability associated with interdependent infrastructure systems. So a framework of analysis is required. This paper takes the power and water systems of a major city in China as an example and develops a framework for the analysis of the vulnerability of interdependent infrastructure systems. Four interface design strategies based on distance, betweenness, degree, and clustering coefficient are constructed. Then two types of vulnerability (long-term vulnerability and focused vulnerability) are illustrated and analyzed. Finally, a method for ranking critical components in interdependent infrastructures is given for protection purposes. It is concluded that the framework proposed here is useful for vulnerability analysis of interdependent systems and it will be helpful for the system owners to make better decisions on infrastructure design and protection. 相似文献
986.
用流变震荡模式研究了10 wt%浓度的弹道明胶在冷却和等温下的老化行为.对明胶从sol-gel点冷却到某个目标温度的过程,通过不同冷却速率的实验,建了一个弹性模量与温度的线性关系.不同温度下明胶的等温老化实验表明,弹性模量-时间曲线具有相似的形状.依据Normand提出的二级反应动力学模型,引入一个表征明胶老化行为的速率常数,构建了一个预测弹道明胶在老化初级阶段的弹性模量演化的模型.该模型中模量-温度关系在初始和无穷大时是直线,其他模量-温度线是近似直线,并交于sol-gel点.老化速率常数和过冷度之间符合Flory-Weaver方程.对弹性模量和老化时间进行归一化处理,可将不同温度下的老化曲线叠加成一条主曲线. 相似文献
987.
A generalization of the Oberbeck–Boussinesq model consisting of a system of steady state multivalued partial differential equations for incompressible, generalized Newtonian of the p-power type, viscous flow coupled with the nonlinear heat equation is studied in a bounded domain. The existence of a weak solution is proved by combining the surjectivity method for operator inclusions and a fixed point technique. 相似文献
988.
For detailed study of complex chemical reactions mechanisms experiment is conducted for selected private reactions. This causes a problem of kinetic parameters getting—the same set of rate constants must describe both public and private reaction stages, and also a general mechanism. In this paper, solution of this problem for a reaction of olefins hydroalumination is proposed. To optimize the computational process a methodology of parallelization is elaborated. On the base of parallel computations, a kinetic model for the reaction assigned is constructed, and on its base, the physical and chemical conclusions about reaction mechanism are done. 相似文献
989.
The optimal information feedback has a significant effect on many socioeconomic systems like stock market and traffic systems aiming to make full use of resources. In this Letter, we study dynamics of traffic flow with real-time information. The influence of a feedback strategy named Corresponding Angle Feedback Strategy (CAFS) is introduced, based on a two-route scenario in which dynamic information can be generated and displayed on the board to guide road users to make a choice. Our model incorporates the effects of adaptability into the cellular automaton models of traffic flow and simulation results adopting this optimal information feedback strategy have demonstrated high efficiency in controlling spatial distribution of traffic patterns compared with the other three information feedback strategies, i.e., vehicle number and flux. 相似文献
990.
J. Cuevas Q.E. Hoq H. Susanto P.G. Kevrekidis 《Physica D: Nonlinear Phenomena》2009,238(22):2216-2226
In the present work, we propose a new set of coherent structures that arise in nonlinear dynamical lattices with more than one component, namely interlaced solitons. In the anti-continuum limit of uncoupled sites, these are waveforms whose one component has support where the other component does not. We illustrate systematically how one can combine dynamically stable unary patterns to create stable ones for the binary case of two-components. For the one-dimensional setting, we provide a detailed theoretical analysis of the existence and stability of these waveforms, while in higher dimensions, where such analytical computations are far more involved, we resort to corresponding numerical computations. Lastly, we perform direct numerical simulations to showcase how these structures break up, when they are exponentially or oscillatorily unstable, to structures with a smaller number of participating sites. 相似文献